镧系元素
发光
转化式学习
聚合物
材料科学
配位复合体
离子
能量转移
纳米技术
化学
工程物理
化学物理
物理
有机化学
光电子学
社会学
冶金
复合材料
教育学
金属
作者
Yasuchika Hasegawa,Yuichi Kitagawa
标识
DOI:10.1016/j.jphotochemrev.2022.100485
摘要
• One-, two-, and three-dimensional luminescent lanthanide coordination polymers are focused for sensing applications. • Changeable luminescence come from the energy transfer between lanthanide(III) ions and aromatic organic ligands. • Their physical and chemical sensitive luminescence are useful for future sensing applications. The photophysical process of lanthanide(III) ion is based on the 4f-4f transition, which is the Laporte forbidden with narrow emission band and long emission lifetime. The 4f-4f emission process is affected by introducing aromatic organic ligands. In this review, recent progress of one-, two-, and three-dimensional polymer-typed lanthanide complexes, luminescent lanthanide coordination polymers, are focused for physical and chemical sensing applications. Their changeable luminescence depended on the physical and chemical environments come from the energy transfer between lanthanide(III) ions and aromatic organic ligands. The characteristic physical (temperature, pressure, pH and mechanical force) and chemical (adsorption of metal ions and molecules) sensitive luminescence of lanthanide coordination polymers are useful for future sensing applications.
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