环氧树脂
多元醇
玻璃化转变
聚氨酯
差示扫描量热法
极限抗拉强度
材料科学
聚酯纤维
胶粘剂
复合材料
粘附
高分子化学
聚合物
物理
热力学
图层(电子)
作者
Boo Young Jeong,Jung Mi Cheon,Jae Hwan Chun
标识
DOI:10.1080/15421406.2016.1201397
摘要
ASBTRACTIn this study, waterborne polyurethanes (WPUs) with an epoxy group and improved hydrolysis resistance and adhesion were synthesized using a polyester polyol, epoxy resin, 4,4-dicyclohexylmethane diisocyanate, and dimethylol propionic acid (DMPA). The properties of the WPU were evaluated by differential scanning calorimetry, tensile strength, elongation, hardness and adhesion strength. The glass transition temperature (Tg) of the synthesized WPU was approximately −50°C. The Tg and tensile strength increased with increasing epoxy resin content while the elongation decreased. The optimum adhesion was achieved with a polyol:epoxy ratio of 99:1.
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