化学
部分
齿合度
磷化氢
钯
配体(生物化学)
铑
路易斯酸
过渡金属
药物化学
金属
催化作用
高分子化学
立体化学
有机化学
受体
生物化学
作者
Noriyuki Suzuki,Satoru Yoneyama,Keisuke Sato,Keisuke Shiba,Takuro Nakayama,Yukina Uematsu,Keigo Sakurai
标识
DOI:10.1016/j.jorganchem.2022.122531
摘要
Multidentate ligands that are comprised of an O,N,O-tridentate coordinating moiety and a phosphine group were synthesized. Some heterobimetallic complexes of these ligands were prepared by a simple method, i.e., first by mixing the ligand and one metal source, then adding another metal source. The O,N,O-moiety selectively coordinated to oxophilic metals such as aluminum, titanium and niobium, while the P moiety, softer Lewis base, selectively captured late transition metals such as palladium and rhodium. Initial attempts were made on a few catalytic reactions with the heterobimetallic complexes.
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