电解质
阳极
阴极
锂(药物)
相间
化学工程
电池(电)
材料科学
溶解
化学
金属锂
金属
快离子导体
高压
无机化学
电压
电极
冶金
电气工程
有机化学
物理化学
功率(物理)
内分泌学
工程类
生物
医学
物理
量子力学
遗传学
作者
Fengwei Bai,Yan Li,Ziyu Chen,Yongchao Zhou,Chengzong Li,Tao Li
标识
DOI:10.1016/j.jpowsour.2022.232045
摘要
High-voltage lithium (Li)-metal batteries with cell-level energy density over 350 Wh kg−1 are promising energy storage systems. However, the aggressive interphase chemistries associated with highly reactive Li-metal anode and high-voltage cathodes impede their practical applications. Herein, we demonstrate the targeted stabilization of solid electrolyte interphase (SEI) and cathode electrolyte interphase (CEI) in high-voltage Li-metal batteries by asymmetrically sustained-releasing different additives. An asymmetric sustained-release film loaded with lithium bis-(oxalate)borate (LiBOB) and LiNO3 on each side is investigated as a proof-of-concept. The sustained-releasing of LiBOB and LiNO3 can maintain a localized concentration at the high-voltage cathode and Li-metal anode fronts respectively, thus forming a stable B-containing CEI and N-containing SEI. As such, issues like dendrites growth, parasitic side reactions and transition metals dissolution under high-voltage are addressed simultaneously. Based on this strategy, the 30 μm Li|LiNi0.5Co0.2Mn0.3O2 (4.1 mAh cm−2) batteries deliver a capacity retention of 80% after 173 cycles under a cut-off voltage of 4.5 V.
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