Hyperbranched Polymers for Organic Semiconductors

Abstract Hyperbranched polymers (HBPs) have attracted increasing attention owing to their distinct highly branched topological structures, resulting in unique properties and wide applications in organic semiconductors (OSCs). In this Review, recent progress in functional HBPs is outlined in the field of OSCs, including organic light‐emitting diodes (OLEDs), organic photovoltaics (OPVs), dye‐sensitized solar cells (DSSCs), and organic field effect transistors (OFETs), among others. Prospects of HBPs‐based materials in OSCs are examined. The results revealed that multi‐dimensional topologies not only regulate the electron (hole) transport but also adjust the film morphology, thereby affecting the efficiency and long life of organic electronic devices. Many studies showed the usefulness of HBPs as hole transport materials but reports dealing with n ‐type and ambipolar materials are still lacking. In addition, the interchain covalent bond in hyperbranched polymers could mitigate the damage caused by stretching, conducive to building stable flexible stretchable devices with long‐term durability and good safety under harsh environmental conditions. Overall, the flexible stretchable design may enrich the applications of HBPs in organic semiconductors and provide new ideas for guiding the future design of functional organic semiconductor materials.