Photopatterned Anchoring Stabilizing Monodomain Blue Phases

Blue phase liquid crystals (BPLCs) are chiral self-assembled three-dimensional (3D) periodic structures which have attracted a lot of attention due to their electro-optical properties, relevant for tunable soft photonic crystals and fast-response displays. However, to realize this application potential, controlling the BPLC alignment at the surfaces is crucial, and one way to obtain the desired alignment is by photoalignment patterning. In this article, monodomain BPLC samples with controlled orientation are achieved by imposing different alignment patterns that have a periodicity that is compatible with the size of the BPLC unit cell, using two-step photoalignment with polarized ultraviolet (UV) light. Experiments are complemented by numerical simulations to design striped surface alignment patterns, which induce specific director orientations on the boundary layer of the confined BPLC. By designing the patterns and matching the periodicity to a specific BP material, we can control the orientation of the blue phase unit cell lattice in the sample, including the azimuthal angle. The orientation is measured by the Kossel patterns and matches the optimal configuration predicted by stability analysis using Landau–de Gennes free energy modeling. The detailed structure and reduced symmetry of the BP near the surface are investigated, and the corresponding (meta)stable structures are demonstrated. Overall, we demonstrate that two-step photoalignment patterning is a reliable, relatively simple, and reconfigurable method to achieve a high-quality monodomain BP with controlled and tunable crystalline orientation.