Unlocking the potential of MOF-Derived Carbon-Based nanomaterials for water purification through advanced oxidation processes: A comprehensive review on the impact of process parameter modulation

Metal-organic framework-derived carbon-based nanomaterials (MOF-derived CBNs) have been widely documented in water treatment due to their outstanding merits including high specific surface area, adjustable pore size, and high electrical conductivity. In particular, the process parameter plays a pivotal role in the physicochemical properties of MOF-derived CBNs. This paper provides a comprehensive overview on the synthesis and regulation in MOF-derived CBNs (including metal oxides/carbon, metallic carbon, and metal-free porous carbon). Emphasis is put on the process parameters (Temperature, atmosphere, heating rate and pyrolysis time) deployed for MOF-derived CBNs. In addition, significant advances of MOF-derived CBNs in the field of various advanced oxidation processes (AOPs) as well as their stability/recyclability in real wastewater treatment have been critically discussed. The relationship between chemical properties and process parameters of MOF-derived CBNs is thoroughly examined. By identifying the current challenges and unveiling future prospects of MOF-derived CBNs, this review provides practical guide for the delicate design and controllable fabrication of MOF-derived CBNs by rational modulation of process parameters. This may contribute to the development of more efficient and sustainable water treatment, bringing a profound impact on our society by addressing the global water crisis and the associated sustainability challenges.