矫顽力
纳米晶材料
材料科学
结晶
合金
非晶态金属
退火(玻璃)
无定形固体
冶金
化学工程
结晶学
凝聚态物理
纳米技术
化学
工程类
物理
作者
Minhao Han,Cheng Sun,Meng Yang,Chekai Liu,Wenfeng Zhang,Huyang Li,Hongjie Xu,Tao Zhang
标识
DOI:10.1016/j.jnoncrysol.2023.122352
摘要
Microalloying is an efficient strategy to promote nano-crystallization of Fe-based amorphous alloys to improve soft magnetic properties. Here, the Fe-P-C-B amorphous alloy is selected as a typical system to investigate the effect of microalloying of immiscible elements (In and Sn) and miscible elements (Al, Ga and Ge) in Fe on crystallization behavior and soft magnetic properties of Fe-based amorphous alloys. Microalloying of immiscible elements leads to slightly increased energy barrier for α-Fe nuclei growth as evaluated by Kissinger equation, yielding fine and uniform α-Fe nanograins and low coercivity after annealing. In contrast, miscible elements cause high growth energy barrier, resulting in few huge α-Fe grains and large coercivity. This work suggests a strategy of obtaining amorphous-nanocrystalline alloys with good magnetic properties by microalloying of immiscible elements.
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