Impact of nucleation temperature on growth uniformity of GaN on 4-inch dome-patterned sapphire substrate

成核 材料科学 蓝宝石 半径 基质(水族馆) 光电子学 位错 图层(电子) 结晶学 复合材料 光学 热力学 化学 地质学 计算机安全 计算机科学 激光器 海洋学 物理
作者
Nor Syafiqah Azmi,Muhammad Naim Mazlan,Mohd Ikram Md Taib,M.A. Ahmad,Mohd Shahrul Nizam Samsuri,Marwan Mansor,Muhammad Iznul Hisyam,Ahmad Shuhaimi,N. Zainal
出处
期刊:Materials Science in Semiconductor Processing [Elsevier BV]
卷期号:173: 108177-108177 被引量:2
标识
DOI:10.1016/j.mssp.2024.108177
摘要

Considerable demands for energy-efficient visible LEDs nowadays have led to a pressing need for high-quality GaN/sapphire templates with large diameters. One of the major challenges to achieve the goal is to obtain good growth uniformity across the entire area of the templates. This paper attempts to improve the growth uniformity for GaN layers on 4-inch dome-patterned sapphire substrate (DPSS) by optimising the GaN nucleation temperature. Here, the nucleation temperature was varied at 520 °C, 550 °C, 570 °C, 590 °C, and 620 °C. In comparison to the case with 520 °C and 620 °C nucleation, the threading dislocation density (TDD) at three different positions (i.e. centre, half-radius on the right side and half-radius on the left side) of the GaN layers grown with 550 °C–590 °C nucleation was relatively lower and the result was consistent among the positions. Meanwhile, the average in-plane strain was higher for these GaN layers compared to the case with 520 °C and 620 °C nucleation. This might be associated with the improvement of the crystalline structure of the layers. Moreover, for the GaN layers with the nucleation of 520 °C–590 °C, the surface was atomically smoother and showed step-flow characteristics at the three positions. It can be suggested that the nucleation at 520 °C–590 °C favoured the growth on the trenches rather than the sidewalls, thereby suppressing multiple growth orientations. Subsequently, an InGaN blue LED was grown on GaN layer with the optimised nucleation temperature. It was found that the electrical and optical characteristics of different LED chips are fairly uniform.
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