Abundant Exterior/Interior Active Sites Enable Three-Dimensional PdPtBiTe Dumbbells C–C Cleavage Electrocatalysts for Actual Alcohol Fuel Cells

Developing high-activity electrocatalysts is of great significance for the commercialization of direct alcohol fuel cells (DAFCs), but it still faces challenges. Herein, three-dimensional (3D) porous PdPtBiTe dumbbells (DBs) were successfully fabricated via the visible photoassisted method. The alloying effect, defect-rich surface/interface and nanoscale cavity, and open pores make the 3D PdPtBiTe DBs a comprehensive and remarkable electrocatalyst for the C1–C3 alcohol (ethanol, ethylene glycol, glycerol, and methanol) oxidation reaction (EOR, EGOR, GOR, and MOR, respectively) in an alkaline electrolyte, and the results of in situ Fourier transform infrared spectra revealed a superior C–C bond cleavage ability. The 3D PdPtBiTe DBs exhibit ultrahigh EOR, EGOR, GOR, and MOR mass activities of 25.4, 23.2, 16.8, and 18.3 A mgPd + Pt–1, respectively, considerably surpassing those of the commercial Pt/C and Pd/C. Moreover, the mass peak power densities of 3D PdPtBiTe DBs in actual ethanol, ethylene glycol, glycerol, or methanol fuel cells increase to 409.5, 501.5, 558.0, or 601.3 mW mgPd + Pt–1 in O2, respectively. This study provides a new class of multimetallic nanomaterials as state-of-the-art multifunctional anode electrocatalysts for actual DAFCs.