Electrocatalytic nitrate-to-ammonia conversion on CoO/CuO nanoarrays using Zn–nitrate batteries

Zn-NO3- batteries can generate electricity while producing NH3 in an environmentally friendly manner, making them a very promising device. However, the conversion of NO3- to NH3 involves a proton-assisted 8-electron (8e-) transfer process with a high kinetic barrier, requiring high-performance catalysts to realize the potential applications of this technology. Herein, we propose a heterostructured CoO/CuO nanoarray electrocatalyst prepared on a copper foam (CoO/CuO-NA/CF) that can electrocatalytically and efficiently convert NO3- to NH3 at low potential and achieves a maximum NH3 yield of 296.9 μmol h-1 cm-2 and the Faraday efficiency (FE) of 92.9% at the -0.2 V vs. reversible hydrogen electrode (RHE). Impressively, Zn-NO3- battery based on the monolithic CoO/CuO-NA/CF electrode delivers a high NH3 yield of 60.3 μmol h-1 cm-2, FENH3 of 82.0%, and a power density of 4.3 mW cm-2. This study provides a paradigm for heterostructured catalyst preparation for the energy-efficient production of NH3 and simultaneously generating electrical energy.