Construction of novel BiOI/CuInS2/ZnO Dual S-scheme charge transfer pathway for efficient antibiotic degradation

The present work explored the photocatalytic activity of BiOI-CuInS2-ZnO ternary heterojunction for the photodegradation of the tetracycline (TCl). The bare photocatalysts were prepared via hydrothermal method while the ternary heterojunction was synthesized using simple physical mixing route. The ternary heterojunction of BiOI, CuInS2 and ZnO followed the S-scheme charge transfer pathway exhibiting superior photodegradation ability compared to other synthesized photocatalysts. The attained degradation efficiency of BiOI-CuInS2-ZnO S-scheme ternary heterojunction was 96.75 % within 90 min of light illumination which was much higher than other photocatalysts. Electron spin resonance (ESR) investigations and scavenging experiment indicated that •O2−, and •OH radicals plays an important role in photodegradation of TCl. Furthermore, the structural analysis of synthesized bare photocatalysts was also done via density functional theory (DFT) calculations. The results showed that after the formation of S-scheme heterojunction, the ternary heterojunction showed lower recombination rate (validated via PL analysis) with boosted charge carriers separation rate (confirmed through EIS and TPR analysis) and light absorption ability. This had led to upgradation in photodegradation efficiency of ternary BiOI-CuInS2-ZnO photocatalyst. The reusability test of the photocatalysts confirmed excellent stability of ternary photocatalysts with 90.25 % degradation rate up to five catalytic cycles.