Effects of glycols on Fischer–Tropsch synthesis activity and coordination structure of Co species in Co/SiO2: Mechanism for enhanced dispersion of Co0 nanoparticles

煅烧 催化作用 三甘醇 色散(光学) 化学 水溶液 摩尔浓度 纳米颗粒 聚合物 摩尔比 高分子化学 无机化学 有机化学 材料科学 纳米技术 物理 光学
作者
Naoto Koizumi,Shigenobu Suzuki,Satoshi Niiyama,Yukiya Ibi,Takayoshi SHINDO,Muneyoshi Yamada
出处
期刊:Applied Catalysis A-general [Elsevier BV]
卷期号:395 (1-2): 138-145 被引量:11
标识
DOI:10.1016/j.apcata.2011.01.035
摘要

Co/SiO2 catalysts with higher dispersion of Co0 as well as high reducibility of Co were prepared by impregnation using an aqueous solution containing Co nitrate and a glycol under different glycol/Co2+ molar ratios. Glycols with different structures, i.e., straight chain and branched ones, were used for preparation of the catalysts to help understand the fundamental role of the glycols. The CO conversion was enhanced in the presence of these glycols. The highest conversion was around 60% under 503 K and 1.1 MPa regardless of the structures of the glycols, whereas the optimum glycol/Co2+ molar ratio for the highest conversion shifted toward higher values with decreasing molecular weight of the glycols. On the other hand, these conversions fell on one curve irrespective of the structures of the glycols when plotted against the C/Co2+ atomic ratios of the impregnation solutions, indicating that the C/Co2+ ratio was one of crucial factors for activity enhancement induced by the glycols. Furthermore, XRD and Co K-edge EXAFS measurements revealed that Co3O4 species with smaller sizes was formed after calcination in the presence of the glycols. Size of Co3O4 species fell on one curve when plotted against the C/Co2+ atomic ratios, which was consistent well with activity data. FT-IR measurements also provided evidence that Co species interacted with triethylene glycol (TEG) derivatives during calcination in the range of 400–470 K. In analogy to the polymerizable complex method, it was considered that this interaction included polymer complex-like species, in which Co species was immobilized in network of cross-linked structures formed by ester polymerization of TEG and dicarboxylic acid derived from TEG, resulting in the formation of smaller Co3O4 species after calcination, and the smaller Co0 nanoparticles after H2 reduction, i.e., enhanced FTS activity.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
大气萤完成签到,获得积分20
1秒前
1秒前
我ppp完成签到 ,获得积分10
1秒前
2秒前
易燃物品完成签到,获得积分10
2秒前
Hello应助Ther采纳,获得10
4秒前
CherylZhao完成签到,获得积分10
5秒前
Galato发布了新的文献求助10
6秒前
颜愫完成签到,获得积分10
6秒前
安详向日葵完成签到 ,获得积分10
7秒前
拼搏的白云完成签到,获得积分10
7秒前
852应助hhh采纳,获得10
7秒前
李白白白完成签到,获得积分10
7秒前
王手完成签到,获得积分10
7秒前
8秒前
一人完成签到,获得积分10
9秒前
do0完成签到,获得积分10
10秒前
yar应助xlz110采纳,获得10
10秒前
NexusExplorer应助落寞凌波采纳,获得10
12秒前
量子星尘发布了新的文献求助10
15秒前
123完成签到 ,获得积分10
15秒前
哈哈呵完成签到,获得积分10
15秒前
15秒前
Rylee完成签到,获得积分10
15秒前
Jiro完成签到,获得积分10
17秒前
我ppp发布了新的文献求助60
18秒前
19秒前
纳米酶催化完成签到,获得积分10
20秒前
20秒前
John完成签到,获得积分10
20秒前
李小强完成签到,获得积分10
21秒前
22秒前
25秒前
落寞凌波发布了新的文献求助10
25秒前
25秒前
26秒前
健壮的尔烟完成签到,获得积分10
26秒前
三三完成签到 ,获得积分10
26秒前
白betty完成签到,获得积分10
28秒前
双儿发布了新的文献求助10
29秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Handbook of Industrial Diamonds.Vol2 1100
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038368
求助须知:如何正确求助?哪些是违规求助? 3576068
关于积分的说明 11374313
捐赠科研通 3305780
什么是DOI,文献DOI怎么找? 1819322
邀请新用户注册赠送积分活动 892672
科研通“疑难数据库(出版商)”最低求助积分说明 815029