对映选择合成
化学
催化作用
绝对构型
立体化学
氨基酸
有机化学
生物化学
作者
Bing‐Feng Shi,Yanghui Zhang,Jonathan Lam,Dong‐Hui Wang,Jin‐Quan Yu
摘要
Pd(II)-catalyzed enantioselective C−H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C−H insertion intermediate.
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