超级电容器
电容
材料科学
电解质
聚苯胺
电极
石墨烯
储能
聚乙烯醇
基质(水族馆)
光电子学
复合材料
纳米技术
化学工程
聚合物
化学
量子力学
海洋学
物理
地质学
工程类
物理化学
功率(物理)
聚合
作者
Ge Jin,Minshen Zhu,Eric Eisner,Yin Yin,Haiyun Dong,Dmitriy D. Karnaushenko,Daniil Karnaushenko,Feng Zhu,Libo Ma,Oliver G. Schmidt
出处
期刊:Small
[Wiley]
日期:2021-05-12
卷期号:17 (24)
被引量:29
标识
DOI:10.1002/smll.202101704
摘要
Abstract Imperceptible electronics will make next‐generation healthcare and biomedical systems thinner, lighter, and more flexible. While other components are thoroughly investigated, imperceptible energy storage devices lag behind because the decrease of thickness impairs the area‐specific energy density. Imperceptible supercapacitors with high area‐specific capacitance based on reduced graphene oxide/polyaniline (RGO/PANI) composite electrodes and polyvinyl alcohol (PVA)/H 2 SO 4 gel electrolyte are reported. Two strategies to realize a supercapacitor with a total device thickness of 5 µm—including substrate, electrode, and electrolyte—and an area‐specific capacitance of 36 mF cm −2 simultaneously are implemented. First, the void volume of the RGO/PANI electrodes through mechanical compression is reduced, which decreases the thickness by 83% while retaining 89% of the capacitance. Second, the PVA‐to‐H 2 SO 4 mass ratio is decreased to 1:4.5, which improves the ion conductivity by 5000% compared to the commonly used PVA/H 2 SO 4 gel. Both advantages enable a 2 µm‐thick gel electrolyte for planar interdigital supercapacitors. The impressive electromechanical stability of the imperceptible supercapacitors by wrinkling the substrate to produce folds with radii of 6 µm or less is demonstrated. The supercapacitors will be meaningful energy storage modules for future self‐powered imperceptible electronics.
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