液晶
凝聚态物理
不稳定性
挠曲电
双稳态
材料科学
弯曲分子几何
各向异性
偏斜
拓扑缺陷
偶极子
光学
物理
机械
量子力学
复合材料
光电子学
作者
Pramod Tadapatri,K. S. Krishnamurthy,W. Weißflog
出处
期刊:Soft Matter
[The Royal Society of Chemistry]
日期:2011-11-28
卷期号:8 (4): 1202-1214
被引量:19
摘要
We examine here the Bobylev–Pikin flexoelectric instability in an initially planar monodomain of a bent-core nematic liquid crystal, which is negative in conductivity and dielectric anisotropies. Experiments employing dc excitation reveal the domain density to be linear in field, as predicted; however, the instability threshold has a negative temperature coefficient indicating the effective flexomodulus as nonquadratic in order parameter. The dc threshold is also determined as a function of simultaneously acting ac voltage; a theoretical fit is found for the data taking into account elastic anisotropy, whereby the relevant flexoelectric and elastic parameters are estimated. Remarkable morphological changes occur under an increasing field. Half-strength disclinations of opposite topological charge evolve within the flexostructure rendering the wavevector orientation degenerate in the layer plane. Dipolar and quadrupolar topological defect patterns, akin to the singularities in cholesteric fingerprint texture, lead finally to fan like objects. The morphological equivalence between the periodic flexoelectric state and a layered lattice as realized here is attributable to a much lower energy of bend type distortion compared to splay, unlike in a calamitic.
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