A Novel 3D CuI Metal–Organic Framework with Middle‐Size Channels Despite the Sixfold ThSi2 Interpenetrating Topological Structure

Abstract A new univalent copper coordination polymer with an unusual asymmetric ThSi 2 topological structural network was synthesized and 1D middle‐size channels were found despite the sixfold ThSi 2 interpenetrating topological structure. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)