超级电容器
微球
电容
纳米颗粒
电导率
材料科学
化学工程
功率密度
电流密度
纳米结构
碱金属
基质(水族馆)
碳纤维
纳米技术
复合材料
化学
电极
复合数
功率(物理)
工程类
物理化学
有机化学
地质学
物理
海洋学
量子力学
作者
Junye Zhang,Hao Guo,Fan Yang,Mingyue Wang,Tingting Zhang,Hao Zhang,Wu Yang
标识
DOI:10.1002/celc.202101523
摘要
Abstract The application of Ni‐MOF in supercapacitors has received widespread attention, but its poor conductivity and bad stability hinder its application. Therefore, Ni‐MOF derived CMs@Ni(OH) 2 /NiSe with a core‐shell structure was designed. Here, carbon microspheres (CMs) were explored as the conductive substrate to enhance the stability and in situ prepared Ni‐MOF was anchored on the surface of CMs. Then, alkali‐treatment and selenylation were carried out on CMs@Ni−MOF to improve stability and conductivity. The obtained core‐shell nanostructure material possesses a high contact area, excellent synergistic effect and can provide more reactive active sites. The prepared CMs@Ni(OH) 2 /NiSe shows a higher specific capacitance (2106 F g −1 ) and excellent cycling performance with a capacitance retention of 95 % after 30000 cycles. Furthermore, the assembled CMs@Ni(OH) 2 /NiSe//AC device delivers a high energy density of 70.84 Wh kg −1 at the power density of 756.8 W kg −1 and maintains 100 % of the initial capacitance after 40000 cycles.
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