电化学能量转换
介电谱
电催化剂
循环伏安法
电化学电池
氧还原反应
电化学
电化学动力学
阴极
计算机科学
纳米技术
材料科学
电极
化学
物理化学
作者
Narayanamoorthy Bhuvanendran,Sabarinathan Ravichandran,Qian Xu,T. Maiyalagan,Huaneng Su
标识
DOI:10.1016/j.ijhydene.2021.12.072
摘要
Oxygen reduction reaction (ORR) is a vital electrochemical reaction for energy conversion that has fascinated the interest of materials researchers to promote active and cost-effective electrocatalysts with improved reaction kinetics. Numerous, researches have been undertaken to achieve the desired characteristic cathode materials to revolutionize energy conversion devices including fuel cells and metal-air batteries (where ORR occurs). More importantly, the evaluation of electrocatalyst efficiency for ORR using typical electrochemical experiments, data collection, and analysis must be performed systematically and uniformly. This review provides a systematic guide to assess the electrochemical efficiency because it includes standard and widely recognized experimental protocols for each electrochemical technique, as well as easy-to-follow lab procedures and a detailed analysis of essential kinetic ORR parameters with a theoretical framework. The major function of each electrode in cyclic voltammetry, hydrodynamic linear scan voltammetry with rotating disc electrodes, and electrochemical impedance spectroscopy for ORR were demonstrated, as well as the construction of a three-electrode electrochemical cell. By following standard protocols and experimental procedures, an aspiring electrochemist would be capable to enforce fundamental and advanced electrochemical techniques much efficiently in their understanding of ORR kinetics evaluation.
科研通智能强力驱动
Strongly Powered by AbleSci AI