Corrugated 1D Hybrid Metal Halide [C6H7ClN]CdCl3 Exhibiting Broadband White-Light Emission

Organic-inorganic hybrid metal halides (OIMHs) exhibiting white-light emission are a splendid class of emitters and are regarded as desired phosphors for solid-state lighting applications. Here we report a single-component white-light-emitting hybrid metal halide, namely, [C₆H₇ClN]CdCl₃ (C₆H₇ClN = 4-(chloromethyl)pyridinium), which features a corrugated 1D anionic double chain composed of edge-shared CdCl₆ octahedrons and exhibits broadband white-light emission with a photoluminescence quantum yield of 12.3% under 365 nm UV light irradiation. Density functional theory calculations and temperature-dependent emission spectral analysis unveil that the broadband emission of [C₆H₇ClN]CdCl₃ is ascribed to self-trapped excitons. Moreover, a single-component white-light-emitting diode device with a correlated color temperature of 5214 K and color rendering index of 83.7 can be fabricated via coating [C₆H₇ClN]CdCl₃ on a 365 nm UV light-emitting diode chip. Such a promising luminescent material provides guidance for the design and synthesis of OIMHs with unique structures and desired properties.