阳极
材料科学
电极
电化学
多孔性
石墨
电池(电)
水溶液
化学工程
复合材料
工艺工程
化学
功率(物理)
物理
物理化学
工程类
量子力学
作者
Andreas Altvater,Julian Klemens,Julian Borho,Anna Smith,Thilo Heckmann,Philip Scharfer,Wilhelm Schabel
标识
DOI:10.1002/ente.202301272
摘要
The drying of solvent‐processed electrodes is a critical process step in the manufacturing of lithium‐ion batteries. The technology used to introduce the energy required for drying into the material, combined with the specified process parameters, significantly influences the resulting electrode properties. A major challenge is to counteract binder migration effects that may occur during drying of the porous electrode structure, causing a decrease in adhesion and electrochemical performance, especially for high drying rates. From this motivation, investigations on the influence of process design during near‐infrared drying of aqueous‐processed graphite anodes are carried out. A multistage drying design with varying parameters in specific drying sections with energy input by radiation is applied. The results show that the specific application of a three‐stage drying profile in combination with energy input by radiation enables a significant decrease in drying time by at least 60% while the electrode properties can be preserved. These findings indicate a beneficial development of binder distribution as a consequence of multistage NIR drying, evidenced by adhesion and electrochemical performance. Finally, the application of the multistage drying profile is theoretically transferred to an industrial‐scale roll‐to‐roll dryer, whereby the necessary dryer length can be reduced by 53%.
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