金属有机骨架
催化作用
Atom(片上系统)
纳米技术
材料科学
多相催化
金属
化学
化学工程
有机化学
冶金
吸附
计算机科学
工程类
嵌入式系统
作者
Qijie Mo,Chunying Chen,Sihong Li,Jiewei Liu,Li Zhang,Cheng‐Yong Su
标识
DOI:10.1002/cctc.202301753
摘要
Abstract Metal single‐atom catalysts (SACs) play an essential role in small molecule related energy conversion. Metal‐organic frameworks (MOFs), which contain the highly ordered arrays of organic linkers and metal nodes, as well as the clearly defined pore structures, are considered as an ideal platform to fabricate atomically dispersed metal sites. In this review, we summarize the approaches for fabricating MOF‐based SACs by utilizing their structure characteristics. A brief discussion is also given about the feasible techniques to characterize SACs. A series of representative examples of MOF‐based SACs and their energy‐related applications, mainly in photocatalysis and electrocatalysis, are discussed. The challenges and future development opportunities of MOF‐based SACs are highlighted.
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