纳米花
抗坏血酸
电化学
检出限
电极
选择性
线性范围
化学
材料科学
核化学
化学工程
无机化学
纳米技术
色谱法
生物化学
纳米结构
催化作用
食品科学
工程类
物理化学
作者
Gengan Saravanan,RM. Gnanamuthu,Sanjay Sankaranarayanan,Venumbaka Maneesh Reddy,Bhanu Chandra Marepally,Ravi K. Biroju
标识
DOI:10.1016/j.sna.2023.114232
摘要
Since lower danger of biorecognition element degradation, enzymes-less glucose have the potential for more reliable in vivo activity, but it suffers due to lack of linear response and poor selectivity. We made attempt to improve selectivity, linear response and stability, environmentally benign electrochemical method adopted to fabricate Pt nanoflowers (PtNF) anchored on rGO modified GCE (PtNF-rGO/GCE). The PtNF-rGO/GCE electrode demonstrated good glucose electrooxidation in alkaline solution, with a linear range, sensitivity and detection limit are up to 3.5 mM, 335.5 μA mM−1 cm−1 and 53 μM (S/N = 3) respectively. The PtNF-rGO/GCE electrode is not only selective also inhibit interfering molecules like uric, dopamine, ascorbic acid. This allows for broadly sensitive, work at low-potential, stable, and quick glucose current detection, which is capable for the expansion of non-enzymatic glucose detectors.
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