Nucleation of equiaxed δ-ferrite by accelerating TiN formation controlled by oxide during welding of ferritic stainless steel

The accelerating effect of oxides on TiN formation to promote the nucleation of equiaxed ferrite was investigated under simulated gas tungsten arc (GTA) welding conditions. This revealed that the formation of oxides such as Ti2O3, (Ti, Al)2O3, and MgAl2O4 is essential for the solidification of equiaxed δ-ferrite. MgAl2O4 significantly accelerates the formation of TiN and produces a fine-grained equiaxed structure. Minor alloying with Ti, Al, and Mg significantly influenced the composition and crystal structure of the oxides. Ti2O3 and (Ti, Al)2O3 were identified as corundum structures with the same orientation relationship as TiN on the {0001} crystal plane. Ti2O3 and (Ti, Al)2O3 could act as heterogeneous nuclei for TiN because low lattice misfits of 0.6% and 0.6–8.1% could be reached for Ti2O3 and (Ti, Al)2O3 for {0001}oxide//{111}TiN and [10–10]oxide//[110]TiN, respectively. Spinel type MgAl2O4 was found to have a fully paralleled orientation relationship with TiN, resulting in a 4.8% misfit with TiN in each crystal plane. This indicates that all the crystal planes of MgAl2O4 could accelerate the formation of TiN. Baker-Nutting orientation relationship was confirmed for TiN and δ-ferrite. Therefore, the TiN formed by oxide acceleration could nucleate δ-ferrite. The multiple accelerating planes of MgAl2O4 and a high quantity of MgAl2O4-TiN as nucleation sites showed an optimal effect on equiaxed solidification under a high-temperature gradient.