Occurrence and correlation of microplastics and dibutyl phthalate in rivers from Pearl River Delta, China

Microplastics have been identified as the novel contaminants in various environments. Phthalates would be released from plasticized microplastics into a riverine environment while transporting to a marine region, but data on their relationship in rivers have been scarce. In this study, the occurrence, distribution and correlation of microplastics and dibutyl phthalate (DBP) in two rivers from the Pearl River Estuary were investigated. The elevated level of DBP in the Qianshan River (2.70 ± 0.20 μg/L) was in alignment with the presence of highest microplastic concentration at the same sampling site (15.8 ± 9.8 items/L). A positive correlation was observed between microplastics and DBP in all sampling sites (p < 0.05). The results showed that UV irradiation from sunlight was a majorly inducing factor of DBP leaching from polyethylene microplastics. The concentrations of chemical additives in some degrees reflect the microplastic pollution, but environmental factors and multidimensionality of microplastics such as residence times and types may cause spatial differences of chemical additives in aquatic systems.