Controlled Distribution of MXene on the Pore Walls of Polyarylene Ether Nitrile Porous Films for Absorption‐Dominated Electromagnetic Interference Shielding Materials

Abstract With the increasing application of electronic devices, absorption‐dominated electromagnetic interference shielding materials (EMISM) have garnered significant attention for preventing secondary electromagnetic pollution. In this study, polyethyleneimine (PEI)‐modified MXene (PEI@MXene) is fabricated and achieved its controlled distribution on the pore walls of polyarylene ether nitrile (PEN) porous films via the phase inversion method (PIM) to obtain a closed porous skeleton of MXene on the pore walls (CPS–MPW). The resulting PEI@MXene/PEN composite film (CFx) exhibited absorption‐dominated EMIS efficiency (EMISE). Attributing to the strong interaction between PEI and the hydrophilic segment of amphiphilic Pluronic F127, with its hydrophobic segment anchored by the PEN matrix, PEI@MXene is directionally distributed on the pore walls of CFx. In addition, resulting from the cladding of MXene with PEI and isolating it with closed honeycomb pores, the obtained CFx are insulators without forming a conductive network. As a result, these CFx demonstrate absorption‐dominated EMISE with the highest SE T of 41.2 dB and coefficient A higher than 0.51. Further continuous hot pressing of CFx results in thinner and denser films with an impressive specific EMISE up to 750 dB cm −1 . The successful fabrication of these CPS–MPW‐type CFx with absorption‐dominated EMISE provides a reference for developing and preparing novel EMISM.