Electronic Metal‐Support Interaction Induces Hydrogen Spillover and Platinum Utilization in Hydrogen Evolution Reaction

Abstract The substantial promotion of hydrogen evolution reaction (HER) catalytic performance relies on the breakup of the Sabatier principle, which can be achieved by the alternation of the support and electronic metal support interaction (EMSI) is noticed. Due to the utilization of tungsten disulfides as support for platinum (Pt@WS 2 ), surprisingly, Pt@WS 2 demands only 31 mV overpotential to attain 10 mA cm −2 in acidic HER test, corresponding to a 2.5‐fold higher mass activity than benchmarked Pt/C. The pH dependent electrochemical measurements associated with H 2 ‐TPD and in situ Raman spectroscopy indicate a hydrogen spillover involved HER mechanism is confirmed. The WS 2 support triggers a higher hydrogen binding strength for Pt leading to the increment in hydrogen concentration at Pt sites proved by upshifted d band center as well as lower Gibbs free energy of hydrogen, favourable for hydrogen spillover. Besides, the WS 2 shows a comparably lower effect on Gibbs free energy for different Pt layers (−0.50 eV layer −1 ) than carbon black (−0.88 eV layer −1 ) contributing to a better Pt utilization. Also, the theoretical calculation suggests the hydrogen spillover occurs on the 3 rd Pt layer in Pt@WS 2 ; moreover, the energy barrier is lowered with increment in hydrogen coverage on Pt. Therefore, the boosted HER activity attributes to the EMSI effect caused hydrogen spillover and enhancement in Pt utilization efficiency.