材料科学
过电位
镍
电催化剂
氢氧化物
氢
氧化物
铂金
氧化镍
析氧
碱性水电解
离解(化学)
无机化学
分解水
非阻塞I/O
纳米技术
化学工程
电解
冶金
催化作用
电解质
电化学
物理化学
电极
有机化学
工程类
化学
生物化学
光催化
作者
Kaixi Wang,Shuo Wang,Kwan San Hui,Junfeng Li,Chenyang Zha,Duc Anh Dinh,Zongping Shao,Bo Yan,Zikang Tang,Kwun Nam Hui
标识
DOI:10.1002/adfm.202211273
摘要
Abstract Platinum (Pt) remains the benchmark electrocatalyst for alkaline hydrogen evolution reaction (HER), but its industry‐scale hydrogen production is severely hampered by the lack of well‐designed durable Pt‐based materials that can operate at ampere‐level current densities. Herein, based on the original oxide layer and parallel convex structure on the surface of nickel foam (NF), a 3D quasi‐parallel architecture consisting of dense Pt nanoparticles (NPs) immobilized oxygen vacancy‐rich NiO x heterojunctions (Pt/NiO x ‐O V ) as an alkaline HER catalyst is developed. A combined experimental and theoretical studies manifest that anchoring Pt NPs on NiO x ‐O V leads to electron‐rich Pt species with altered density of states (DOS) distribution, which can efficiently optimize the d‐band center and the adsorption of reaction intermediates as well as enhance the water dissociation ability. The as‐prepared catalyst exhibits extraordinary HER performance with a low overpotential of 19.4 mV at 10 mA cm −2 , a mass activity 16.3‐fold higher than that of 20% Pt/C, and a long durability of more than 100 h at 1000 mA cm −2 . Furthermore, the assembled alkaline electrolyzer combined with NiFe‐layered double hydroxide requires extremely low voltage of 1.776 V to attain 1000 mA cm −2 , and can operate stably for more than 400 h, which is rarely achieved.
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