Groundwater age and mixing process for evaluation of radionuclide impact on water resources following the Fukushima Dai-ichi nuclear power plant accident

Radionuclide contamination of groundwater causes critical impacts on water resources, human lives, and ecosystems. The intrusion of radionuclides into the groundwater flow system in Fukushima, Japan, could be illuminated by determining groundwater age and mixing processes. To do this, periodical field surveys were conducted in catchments contaminated by the Fukushima Dai-ichi Nuclear Power Plant accident. Sampling began in May 2011, which was 2 months after the disaster, and continued through June 2012. Chlorofluorocarbon (CFCs), tritium, and oxygen and hydrogen stable isotopes were used as environmental tracers. The observed tritium concentrations suggested that the water contained accident-derived radionuclides that exceeded the natural background baseline. Groundwater ages in the selected two headwater catchments were estimated to be between 10 and 26 years by combined use of multiple CFCs concentrations. In addition, the governing groundwater flow system was mostly approximated by a piston flow model; however, modern water fraction was also suggested based on the relationship between CFC-11 and CFC-12. The estimated water age and isotopic signals among stream water, spring water, and groundwater revealed that the intrusion of radionuclides into the groundwater was caused by the mixing between groundwater and modern water sources such as soil water and precipitation with relatively high radionuclide concentrations. This mixing was facilitated by a weathered and fractured granite bedrock and a thin unsaturated subsurface layer in the study area. Continued long-term monitoring of radionuclides in the groundwater will be necessary for water resources management in the future. Radionuclide intrusion into the groundwater is related to the mixing between radionuclide-poor groundwater and modern water with relatively high radionuclide concentration.