超级电容器
电容
材料科学
聚吡咯
乙烯醇
自愈水凝胶
电容感应
复合数
纳米技术
电极
电容器
纳米颗粒
储能
化学工程
复合材料
聚合物
高分子化学
电气工程
电压
化学
聚合
功率(物理)
物理
物理化学
量子力学
工程类
作者
Han Lin,Yueqin Li,Chen Chen,Zichun Lu,Lingke Liu
标识
DOI:10.1016/j.colsurfa.2023.132452
摘要
Developing all-gel supercapacitors with high capacitance and stretchability remains a challenge. Herein, high mass of electroactive anthraquinonemonosulfonate(AQS)-doped polypyrrole (PPy) nanoparticles templated by poly(vinyl alcohol) (PVA) have been loaded into poly(acrylic acid) (PAA) hydrogel. The extra energy storage of AQS significantly enhances the electrochemical performance of the obtained PPy-AQS-PVA/PAA hydrogel electrodes. As a result, the assembled symmetrical supercapacitor can deliver a large areal specific capacitance of 392.5 mF/cm2, a high energy density of 34.89 μWh/cm2 and an enhanced cycling performance with 118% capacitance retention after 5000 CV cycles. Besides, such a device can work normally under various deformations and at extreme temperatures. Notably, the PPy-AQS-PVA/PAA hydrogels exhibit sustainable sensing capability for strain. When integrated the flexible supercapacitor with the strain sensor, a promising self-powered sensing system can monitor both large and subtle human movements accurately. Therefore, the multifunctional conductive PPy-AQS-PVA/PAA hydrogels have great potential in flexible electronic devices.
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