纳米片
共轭体系
两亲性
聚合
聚合物
材料科学
纳米技术
自组装
石墨烯
表面改性
共聚物
化学工程
工程类
复合材料
作者
Daewoong Jang,Jung-Moo Heo,Fadilatul Jannah,Mohammed Iqbal Khazi,Young Ji Son,Jaegeun Noh,Hyosung An,Soon Mo Park,Dong Ki Yoon,Nila Nandha Kadamannil,Raz Jelinek,Jong-Man Kim
标识
DOI:10.1002/anie.202211465
摘要
Creation of new two-dimensional (2D) architectures has attracted significant attention in the field of self-assembly for structural diversity and new functionalization. Although numerous 2D polymer nanosheets have been reported, 2D nanosheets with tubular channels have been unexplored. Herein, we describe a new strategy for the fabrication of stimulus-responsive conjugated polymer 2D nanosheets with hollow cavities. Amphiphilic macrocyclic diacetylenes self-assembled in an aqueous solution in a columnar manner to afford bilayered 2D nanosheets with intrinsically tubular nanochannels. UV-induced polymerization resulted in the generation of blue-colored tubular conjugated polydiacetylene 2D nanosheets. Immobilization of gold nanoparticles, fluorescence labeling with FRET phenomenon and colorimetric DNA sensing were demonstrated with these new 2D nanosheets. In addition, the free NH2 containing polymerized 2D nanosheet was utilized for conductivity behavior and grafting on graphene oxide (GO).
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