钒
材料科学
氧化钒
压力(语言学)
纳米技术
分布(数学)
冶金
数学
语言学
哲学
数学分析
作者
Yuan Gao,Linghan Xia,Junyi Yin,Zihan Gan,Xiang Feng,Guodong Meng,Yonghong Cheng,Xin Xu
标识
DOI:10.1002/smtd.202200999
摘要
Abstract Compared with lithium‐ion batteries (LIBs), aqueous zinc batteries (AZIBs) have received extensive attention due to their safety and cost advantages in recent years. The cathode determines the electrochemical performance of AZIBs to a large extent. Vanadium‐based materials exhibit excellent capacity when used as AZIB cathodes. However, unexpected structural stress is inevitably induced during cycling and high current densities, which can gradually lead to structural deterioration and capacity decay. In fact, the stress/strain distribution in nanomaterials is crucial for electrochemical performance. In this work, the optimized stress distribution of the hierarchical hollow structure is verified by the finite element simulation of COMSOL software firstly. Guided by this model, a simple solvothermal method to synthesize hierarchical hollow vanadium oxide nanospheres (VO‐NSs), consisting of ≈10 nm ultrathin nanosheets and ≈500 nm hollow inner cavities, is employed. And a highly disordered structure is introduced to the VO‐NSs by in situ electrochemical oxidation, which can also weaken the structural stress during Zn 2+ insertion and extraction. Benefiting from this unique structure, VO‐NSs exhibit high‐rate and stable Zn 2+ storage capability. The strategy of engineering‐driven material design provides new insights into the development of AZIB cathodes.
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