叠氮化物
苄胺
试剂
深共晶溶剂
化学
氯化胆碱
溶剂
有机化学
酰胺
催化作用
有机合成
环加成
离子液体
产量(工程)
组合化学
共晶体系
材料科学
合金
冶金
作者
Ehsan Kamali,Abolfazl Mohammadkhani,Farzane Pazoki,Akbar Heydari
标识
DOI:10.1002/slct.202204642
摘要
Abstract This study synthesized choline amide as a solvent‐free reagent and ion liquid in one pot to directly create benzylamine without producing associated salts. The synthesis of benzyl azide was also carried out with choline azide solventless, and 1,2,3‐triazole was prepared in the method mentioned. The synthesis of 1,2,3‐triazoles followed the process of a formal benzyl azide cycloaddition. For this purpose, a deep eutectic solvent was used as a catalyst to complete the nitrostyrene process. Both reactions were conducted with a high isolated yield without harmful solvents or catalysts. Eco‐friendly and economically feasible, the method also met environmental standards.
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