Studies on lead sulfide-PbS quantum dot-QD based solar cells have gained considerable attention in recent years. A direct synthesis-DS method has emerged that makes it possible to obtain PbS ink in a single step by eliminating complex synthesis and ligand exchange processes, thus reducing the production cost and time. However, the limited number of studies on cells obtained with this method obscures the high potential of this technique. In this study, various electron-ETL and hole transport layers-HTL were systematically brought together in the SCAPS-1D environment to determine the architecture of the cell with record performance. A photoconversion efficiency-PCE of over 20% was achieved with a cell in which n-type DS PbS inks were combined with TiO