Tough Hydro‐Aerogels with Cation Specificity Enabled Ultra‐High Stability for Multifunctional Sensing and Quasi‐Solid‐State Electrolyte Applications

The anion-specific effects of the salting-in and salting-out phenomena are extensively observed in hydrogels, whereas the cation specificity of hydrogels is rarely reported. Herein, a multi-step strategy including borax pre-gelation, saline soaking, freeze-drying, and rehydrating is developed to fabricate polyvinyl alcohol gels with cation specificity, exhibiting the specific ordering of effects on the mechanical properties of gels as Ca