阴极
材料科学
溶解
钒
水溶液
离子
相(物质)
化学工程
淡出
分析化学(期刊)
冶金
电气工程
化学
计算机科学
物理化学
工程类
有机化学
操作系统
色谱法
作者
Kaiyue Zhu,Weikang Jiang,Zhengsen Wang,Weijian Li,Weili Xie,Hanmiao Yang,Weishen Yang
标识
DOI:10.1002/anie.202213368
摘要
Abstract Aqueous Zn‐ion batteries (ZIBs) are promising candidates for grid‐scale energy storage because of their intrinsic safety, low‐cost and high energy‐intensity. Vanadium‐based materials are widely used as the cathode of ZIBs, especially A 2 V 6 O 16 ⋅ nH 2 O (AVO, A=NH 4 + , Na, K). However, AVO suffers from serious dissolution, phase transformation and narrow gallery spacing (∼3 Å), leading to poor cycling stability and rate capability. Herein, we unveiled the root cause of the performance degradation in the AVO cathode and therefore developed a new high‐performance cathode of ZnV 6 O 16 ⋅ 8H 2 O (ZVO) for ZIB. Through a method of ion exchange induced phase transformation, AVO was converted to hewettite ZVO with larger gallery spacing (∼6 Å) and more stable V 6 O 16 layers. ZVO cathode thus constructed delivers a high capacity of 365 and 170 mAh g −1 at 0.5 and 15 A g −1 , while 86 % and 70 % of its capacity are retained at 0.5 A g −1 after 300 cycles and at 15 A g −1 after 10000 cycles, substantially better than conventional AVO.
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