Significance An ideal Weyl semimetal with high tunability is an undoubtedly important platform for realizing and manipulating exotic quantum properties of topological semimetals. Currently, all the existing nonmagnetic Weyl semimetals are not ideal and out of external control, namely, no couplings to an order parameter. In this work, we report with a topological phase transition diagram the successful realization of a Weyl semimetal phase by chemically engineering the PbTe-SnTe alloy. Furthermore, we demonstrate that the Weyl semimetal phase is strongly coupled with the underlying ferroelectric order, which exhibits turn on/off properties when the ferroelectric order appears/disappears. The Weyl phase is detected experimentally by a Berry curvature–sensitive thermoelectric probe called in-plane Nernst effect, which excludes the Drude response.