Coral-inspired environmental durability aerogels for micron-size plastic particles removal in the aquatic environment

Removing microplastics (MPs) from water has been a huge challenge due to their inherent features including small size and high stability. In this research, inspired by the active adsorption and passive adhesion mechanisms of corals to MPs, a new strategy to fabricate polydopamine enhanced magnetic chitosan (PDA-MCS) aerogels was developed with a target to match the surface properties of MPs, achieving high MPs removal efficiency. PDA-MCS aerogels were highly efficient in adsorbing polyethylene terephthalate (PET) microplastics in water at pH values of 6–9, with a removal efficiency of up to 91.6%. Even after three recycles, PDA-MCS aerogels still displayed comparatively high removal efficiency (83.4%). Kinetic and isothermal experiments showed that the adsorption process was the result of electrostatic interactions and physical adhesion between aerogels and microplastics. Moreover, PDA-MCS aerogels maintained high removal efficiency under simulated environmental conditions, and the removal efficiency of PET, polyethylene (PE) and polystyrene (PS) microplastics in waters reached 97.3%, 94.6%, and 92.3%, respectively. Therefore, high-efficiency environmentally durable aerogels adsorbent materials have the potential for the removal of MPs from the aquatic environment.