Photo-assisted degradation of Rhodamine B by a heterogeneous Fenton–like process: performance and kinetics

This study presents the degradation of rhodamine B (RhB) by photo Fenton-like (PF-like) process under visible light irradiation (λ > 380 nm) using cobalt phosphate microparticles (CoP-MPs). The effects of the initial concentration of RhB, pH value, CoP-MPs dosage, hydrogen peroxide (H2O2) concentration, and salts found in textile wastewater (such as NaNO3, Na2SO4, and NaCl) were investigated in detail. It was found that CoP-MPs can maintain high catalytic activity with wide pH values varying from 4 to 8. This indicated that the use of CoP-MPs overcame the low efficiency of Fenton-like reaction at neutral and even weakly alkaline pH. The PF-like degradation of RhB followed pseudo-first order kinetics in various conditions. Moreover, a comparison of experimental results showed that the PF-like system has good degradation ability for RhB and methyl blue (MB) solution, but is poor for methyl orange (MO) solution. The repeat experiments indicated that the chemical structures of CoP-MPs were stable. Furthermore, the Co2+ ions leaching to the solutions were measured by an inductively coupled plasma mass spectrometer (ICP-MS). Analysis of UV-vis spectra suggested that RhB was degraded by the formation of a series of N-de-ethylated intermediates followed by cleavage of the whole conjugate chromophore structure.HighlightsRhB can be effectively degraded in the PF-like process under visible light irradiation by CoP-MPs.The PF-like process can maintain high catalytic activity at neutral and even weakly alkaline pH.Degradation kinetics exhibited pseudo-first-order kinetics and were influenced by the key parameters.The variation in the UV-vis spectra of RhB was analyzed in detail to infer a possible degradation pathway.