The Origin of Superhydrophobicity for Intrinsically Hydrophilic Metal Oxides: A Preferential O2 Adsorption Dominated by Oxygen Vacancies

Abstract The superhydrophobicity of intrinsically hydrophilic materials is still not well understood. Now, intrinsically hydrophilic metal oxides with different topographic structures are taken as model materials to reveal the origin of their superhydrophobicity. These metal oxides show enhanced hydrophobicity or superhydrophobicity in O 2 relative to that in air, but exhibit superhydrophilic behavior in N 2 . The presence of rich oxygen vacancies greatly enhanced the adsorption of O 2 with an adsorption energy larger than N 2 and H 2 O, resulting in a stable O 2 adsorption rather than air‐trapping within grooves of rough‐textured surfaces, which endows these intrinsically hydrophilic oxides with superhydrophobicity. Our results highlight a further understanding of the origin of superhydrophobicity for intrinsically hydrophilic materials, and is of great significance for designing novel devices with desired wettability.