Surface modification of polyester fabric with plasma pretreatment and carbon nanotube coating for antistatic property improvement

抗静电剂 材料科学 涂层 聚酯纤维 X射线光电子能谱 复合材料 固化(化学) 扫描电子显微镜 碳纳米管 等离子体 表面改性 化学工程 图层(电子) 物理 量子力学 工程类
作者
C.X. Wang,Jingchun Lv,Yu Ren,Tian Zhi,J.Y. Chen,Qingqing Zhou,Zhenqian Lu,Dawei Gao,Limin Jin
出处
期刊:Applied Surface Science [Elsevier BV]
卷期号:359: 196-203 被引量:70
标识
DOI:10.1016/j.apsusc.2015.10.060
摘要

This study introduced a green method to prepare antistatic polyester (PET) fabrics by plasma pretreatment and single-walled carbon nanotube (SWCNT) coating. The influences of plasma conditions and SWCNT coating parameters on antistatic property of PET fabrics were investigated. PET fabrics were pretreated under various plasma conditions such as different treatment times, output powers and working gases, and then SWCNT coating on the plasma treated PET fabrics was carried out by coating-dry-cure using various coating parameters including different SWCNT concentrations, curing times and curing temperatures. PET fabrics were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and volume resistivity. SEM and XPS analysis of the plasma treated PET fabrics revealed the increase in surface roughness and oxygen/nitrogen containing groups on the PET fiber surface. SEM and XPS analysis of the plasma treated and SWCNT coated PET fabrics indicated the SWCNT coating on PET fiber surface. The plasma treated and SWCNT coated PET fabrics exhibited a good antistatic property, which increased and then decreased with the increasing plasma treatment time and output power. The antistatic property of the O2 plasma treated and SWCNT coated PET fabric was better and worse than that of N2 or Ar plasma treated and SWCNT coated PET fabric in the shorter treatment time and the longer treatment time, respectively. In addition, the antistatic property of the plasma treated and SWCNT coated PET fabrics also increased with the increasing SWCNT concentration, curing time and curing temperature in the range studied. Plasma conditions and SWCNT coating parameters had signally influence on the antistatic property of plasma treated and SWCNT coated PET fabrics. Therefore, adequate parameters should be carefully selected for the optimum antistatic property of the plasma treated and SWCNT coated PET fabrics.
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