纳米晶
可见光谱
催化作用
材料科学
光催化
光化学
氧气
析氧
纳米技术
光电子学
化学
电化学
物理化学
电极
生物化学
有机化学
作者
Lianjun Liu,Yuqiu Jiang,Huilei Zhao,Jiatang Chen,Jianli Cheng,Kesong Yang,Ying Liu
标识
DOI:10.1021/acscatal.5b02098
摘要
This work for the first time reports engineered oxygen-deficient, blue TiO2 nanocrystals with coexposed {101}-{001} facets (TiO2–x{001}-{101}) to enhance CO2 photoreduction under visible light. The TiO2–x{001}-{101} material demonstrated a relatively high quantum yield (0.31% under UV–vis light and 0.134% under visible light) for CO2 reduction to CO by water vapor and more than 4 times higher visible light activity in comparison with TiO2 with a single {001} plane or {101} plane and TiO2(P25). Possible reasons are the exposure of more active sites (e.g., undercoordinated Ti atoms and oxygen vacancies), the facilitated electron transfer between {001} and {101} planes, and the formation of a new energy state (Ti3+) within the TiO2 band gap to extend the visible light response. An in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) study was applied to understand the roles of coexposed {001}-{101} facets and Ti3+ sites in activating surface intermediates. The in situ DRIFTS analysis suggested that the coexposed {001}-{101} facets increased the capacity of reversible CO2 adsorption and that the combination of {001}-{101} and Ti3+ enhanced the activation and conversion kinetics of adsorbed species. The visible light responsive TiO2–x{001}-{101} material is not oxidized after long-term exposure to an air environment. This work is a significant contribution to the design of efficient and stable solar fuel catalysts.
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