胶粘剂
均质化(气候)
材料科学
粒径
复合材料
抗剪强度(土壤)
化学工程
环境科学
生态学
生物
工程类
生物多样性
土壤科学
土壤水分
图层(电子)
作者
Yi Zhang,Ruiqing Shi,Yabei Xu,Mingsong Chen,Jieyu Zhang,Qiang Gao,Jianzhang Li
标识
DOI:10.1016/j.jclepro.2020.120336
摘要
Soybean meal (SM), a byproduct of bean oil production, was recycled to develop a bio-adhesive capable of replacing formaldehyde-based wood adhesives. However, SM’s large particle size, uneven particle size distribution, and hydrophilic hydrogen bonds result in SM adhesives’ exhibiting low adhesion stability and poor water resistance. Traditional chemical modification methods do not sufficiently mitigate these complications, and consequently SM adhesives must overcome some significant challenges before they can be considered for industrial application. In this work, we propose a simple, clean and physical high-pressure homogenization (HPH) technology in conjunction with eco-friendly cross-linking to develop a stable high-performance bio-based adhesive. Results showed that HPH treatment reduced the SM’s particle size by 62% and increased the particle size distribution uniformity, which significantly enhanced the adhesive’s bonding stability. Furthermore, many active functional groups inside the soy protein were simultaneously unmasked during HPH, which increased their reactivity with the cross-linker. This facilitated the formation of covalent bond complexes with a denser structure in the adhesive system, thereby improving the SM adhesive’s water resistance. Specifically, after the HPH treatment, the resultant plywood’s wet shear strength marked a 212% increase compared to that of untreated SM adhesive, which meets the requirements for indoor use. Moreover, this method has been successfully applied in pilot scale industrial production, and thereby shows broad prospects for practical application.
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