化学
分子内力
卡宾
四氢异喹啉
催化作用
光化学
立体化学
有机化学
作者
Zhong‐Hua Gao,Zihao Xia,Lei Dai,Song Ye
标识
DOI:10.1002/adsc.202000164
摘要
Abstract An N‐heterocyclic carbene catalyzed photooxidation reaction via intramolecular cross dehydrogenative coupling of tetrahydroisoquinoline‐tethered aldehydes was developed, giving the corresponding oxidative cyclization products in moderate to good yields. This reaction features mild conditions with oxygen as the terminal oxidant in the absence of photocatalyst. magnified image
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