绝对构型
化学
全合成
倍半萜
立体化学
天然产物
绝对(哲学)
萜烯
认识论
哲学
作者
A. Srikrishna,Dattatraya H. Dethe
出处
期刊:Organic Letters
[American Chemical Society]
日期:2003-06-01
卷期号:5 (13): 2295-2298
被引量:47
摘要
The first total synthesis of the sesquiterpene (−)-cucumin H, a linear triquinane isolated from Macrocystidia cucumis, has been accomplished starting from (R)-limonene employing two different cyclopentannulation methodologies, which in addition to confirming the structure also established the absolute configuration of the natural product.
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