Ionic elastomers based on carboxylated nitrile rubber (XNBR) and zinc peroxide: Influence of carboxylic group content on properties

Abstract The properties of ionic elastomers formed in the crosslinking with zinc peroxide are studied in compounds with varying proportions of carboxylic groups in the elastomeric matrix. At the temperature used, 150°C, preferentially ionic bonds were formed. The crosslinking densities and, correspondingly, the physical properties, increased with the acid group content and with the reaction time. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 605–615, 2002; DOI 10.1002/app.10313