检出限
分子印迹聚合物
复合数
纳米化学
傅里叶变换红外光谱
材料科学
荧光
分析化学(期刊)
荧光光谱法
化学
Zeta电位
核化学
纳米颗粒
色谱法
化学工程
纳米技术
选择性
复合材料
有机化学
催化作用
工程类
物理
量子力学
作者
Min Wang,Qifeng Fu,Kailian Zhang,Yuyan Wan,Lujun Wang,Manjie Gao,Zhining Xia,Die Gao
标识
DOI:10.1007/s00604-018-3200-0
摘要
A magnetic molecularly imprinted composite was prepared by reverse microemulsion using carbon dots (CDs), Fe3O4 as the co-nucleus, and a molecularly imprinted polymer (MIP; with 2,4,6-trinitrophenol as the template) acting as recognition sites. The composite of type CD/Fe3O4@MIPs was characterized by transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), zeta potentiometric analysis, X-ray diffraction (XRD) and vibrating sample magnetometry (VSM). The results showed that the composite MIP has a spherical shape with average diameter of 200 nm. They also showed that the composite contains core-shell structures with several Fe3O4 nanoparticles and CDs embedded in each of the microsphere. The composite can extract 2,4,6-trinitrophenol (TNP) and has an imprinting factor of 3.6. It has high selectivity and sensitivity for TNP which acts as a quencher of the fluorescence of the CDs (with excitation/emission maxima at 370/470 nm). The limit of detection of this fluorometric TNP assay is 0.5 nM. The method was successfully applied to the determination of TNP in spiked tap water and river water samples, and recoveries ranged from 89.4% to 108.5% (with an RSD of <6%).
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