电解质
金属锂
复合数
材料科学
锂(药物)
金属
聚合物电解质
化学工程
复合材料
聚合物
电极
离子电导率
化学
冶金
物理化学
内分泌学
工程类
医学
作者
Ji Hu,Wan‐Hui Wang,Xinjun Zhu,Shaobing Liu,Yujiang Wang,Yajuan Xu,Sikai Zhou,Xichan He,Zhigang Xue
标识
DOI:10.1016/j.memsci.2020.118697
摘要
Abstract Herein, a series of one-dimensional silica nanotubes (SNts) with hollow nanostructures and high uniformity are synthesized by etching the rod-shaped nickel-hydrazine complex, and composite polymer electrolytes (CPEs) are prepared by introducing SNts and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) into poly(ethylene oxide) (PEO) skeleton. The CPEs obey Vogel-Tamman-Fulcher empirical equation and the ionic conductivity is demonstrated to be maximum of 4.35 × 10−4 S cm−1 with the longest SNts (270 nm) as fillers at 30 °C, which is significantly higher than that of PEO/LiTFSI (6.13 × 10−8 S cm−1) and PEO/LiTFSI/silica nanoparticles (SNps) (1.07 × 10−6 S cm−1). The connection between SNts among the whole composite contributes the efficient transport pathway to lithium ions. Furthermore, the fabricated cell exhibits good cyclability and rate capability. The SNts based CPEs represent a new design idea for solid-state electrolytes and offers opportunities for lithium metal batteries in the future.
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