集聚经济
烟煤
煤
氧化剂
煤气化
木材气体发生器
熔渣(焊接)
材料科学
流化床
化学工程
冶金
反应性(心理学)
矿物学
废物管理
化学
有机化学
工程类
医学
病理
替代医学
作者
Denghao Jiang,Haixia Zhang,Shengxian Xian,Zhengwang Zhu
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2020-02-20
卷期号:34 (3): 2772-2780
被引量:3
标识
DOI:10.1021/acs.energyfuels.9b03822
摘要
To localize coal utilization, a local Hongshagang bituminous coal (Hc) with low ash fusion temperatures (AFTs) was blended with the Guanghui bituminous coal (Gc). Prior to its application in an industrial fluidized bed gasifier, a series of verification tests were performed in this study for feasibility analysis. The AFTs and CO2 gasification reactivity of blended coal decrease with the increases in the additive amount of Hc. Therefore, the additive amount of Hc was determined to be 10–30% for further bubbling fluidized bed (BFB) gasification. During BFB gasification experiments, the addition of Hc lowered the gasification performance; furthermore, agglomeration and slagging occurred. The deposited slags were examined via SEM, XRF, and XRD to determine the formation mechanism. Specifically, the flux effect of Fe and Na in Hc ash promoted the slagging. The local oxidizing atmosphere in the bottom of the reactor affected the mineral transformation in slags. It changed the contents of crystal phases and led to solidification of liquid phase by comparing XRD results and Factsage calculations. At last, the formation process of slag was described based on the aforementioned experimental phenomena.
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