Synthesis of Mesoporous/Macroporous Microparticles Using Three-Dimensional Assembly of Chitosan-Functionalized Halloysite Nanotubes and Their Performance in the Adsorptive Removal of Oil Droplets from Water

Halloysite nanotubes (HNTs) were assembled into mesoporous/macroporous microparticles (c-g-HNTs MPs) using Pickering template-assisted approach. To unravel the stabilization mechanism in Pickering emulsion form, several emulsions and microparticles were prepared at various conditions and visualized using confocal laser scanning microscopy. The prepared c-g-HNTs MPs were used to treat emulsified oil solutions resulting in a maximum removal efficiency of 94.47%. The kinetics data of oil adsorption onto c-g-HNTs MPs was best fitted by the pseudo-second-order kinetic model (R2 = 0.9983). The maximum monolayer adsorption capacity of oil onto c-g-HNTs MPs as predicted by the multilayer Brunauer–Emmett–Teller model was found to be 788 mg/g. Compared with pristine HNTs, c-g-HNTs MPs exhibited higher self-settleability rates in aqueous solutions as well as in emulsified oil solutions, demonstrating their candidacy for practical water treatment applications. The c-g-HNTs MPs were repeatedly used for five adsorption–desorption cycles with minimal losses noticed in their performance.